Asked by the BBC in an interview whether he will step down, the billionaire conservative leader said: “No.”
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“These problems have been accumulating for the past 30 years,” Pinera said. “I am responsible (for) part of it and I assume my responsibility, but I’m not the only one.”
The violence gripping one of Latin America’s most prosperous countries forced the government to cancel separate international economic and climate summits and open talks with the left-wing opposition.
Chile’s football federation on Tuesday called off an international friendly match with Bolivia slated for the National Stadium in Santiago on November 15.
The decision threw into doubt Santiago’s ability to host the South America Copa Libertadores club championship final on November 23.
South American football authorities were meeting in Asuncion to consider whether to maintain the troubled Chilean capital as the venue for the showpiece final.
Economic slowdown expected
In his interview, Pinera defended his decision to declare a state of emergency but promised to look into allegations of police violence and abuse.
The interview came as the president announced a package of measures for small and medium-sized businesses hit by the unrest.
Some 6,800 companies affected by rioting, looting and fires will benefit from financial aid and tax deductions.
Protesters clashed with police and looted stores at the close of a huge rally on Monday that marked the start of the third week of protests in Santiago.
Tens of thousands of people gathered in the Plaza de Italia, the epicentre of the unrest over economic inequality and a raft of other social woes and tried to march on the presidential palace in downtown Santiago.
Fights broke out with police trying to contain them, with officers firing water cannon and tear gas. One officer was hit in the face with a Molotov cocktail.
Looting and vandalism were reported in the cities of Vina del Mar, Valparaiso and Concepcion.
Protesters organised rallies on Monday under the slogan “This is not over.”
Some citizens returned to work despite the vandalism that has damaged the underground train network.
“There are many alleged complaints about excessive use of force and if that took place I can guarantee you that it will be investigated,” Pinera said.
“There will be no impunity,” he said, defending the stepped-up security measures as “democratic and constitutional.”
Pinera held inconclusive talks with opposition parties last week but made no reference to them in segments of the interview aired by the BBC.
Protesters are calling for constitutional reform. Chile’s current constitution dates back to the 1973-1990 dictatorship of Augusto Pinochet.
A survey by pollster Cadem published on Sunday indicated that 87 percent of Chileans favoured such reforms.
The study indicated Pinera’s approval rating had plunged to 13 percent.
The government said Chile’s economy grew three percent in September but it forecast a contraction of 0.5 percent in October due to the unrest.