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National Coalition chief tells Al Jazeera that opposition is open to dialogue but will not travel to Moscow for talks.
Announcement comes as new video emerges purporting to show opposition fighters announcing their rejection of coalition.
EU foreign ministers say they view the National Coalition to be the "legitimate representatives" of the Syrian people.
Mounzir Makhous was appointed by opposition leader after talks in Paris with President Francois Hollande.
European and Arab ministers meet at Arab League in Cairo to discuss crisis that has reportedly killed 35,000 people.
Sheikh Ahmad Moaz al-Khatib is seen as moderate and charismatic, but some worry about his political inexperience.
Featured on Al Jazeera
At least 25 tax collectors have been killed since 2012 in Mogadishu, a city awash in weapons and abject poverty.
Tokyo government claims its homeless population has hit a record low, but analysts - and the homeless - beg to differ.
3D printers can cheaply construct homes and could soon be deployed to help victims of catastrophe rebuild their lives.
Lack of child protection laws means abandoned and orphaned kids rely heavily on the care of strangers.
 
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