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National Coalition chief tells Al Jazeera that opposition is open to dialogue but will not travel to Moscow for talks.
Announcement comes as new video emerges purporting to show opposition fighters announcing their rejection of coalition.
EU foreign ministers say they view the National Coalition to be the "legitimate representatives" of the Syrian people.
Mounzir Makhous was appointed by opposition leader after talks in Paris with President Francois Hollande.
European and Arab ministers meet at Arab League in Cairo to discuss crisis that has reportedly killed 35,000 people.
Sheikh Ahmad Moaz al-Khatib is seen as moderate and charismatic, but some worry about his political inexperience.
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Muslim volunteers face questioning and threat of arrest, while aid has been disrupted or blocked, charities say.
Six months on, outrage and sorrow over the mass schoolgirl abduction has disappeared - except for families in Nigeria.
ISIL combatants seeking an 'exit strategy' from Mideast conflict need positive reinforcement back home, analysts say.
European nation hit by a wave of Islamophobia as many young fighters join ISIL in Syria and Iraq.
 
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